Party balloons are mostly made of natural latex tapped from rubber trees, and can be filled with air, helium, water, or any other suitable liquid or gas. The rubber's elasticity makes the volume adjustable.When rubber balloons are filled with helium so that they float, they typically retain their buoyancy for only a day or so. The enclosed helium atoms escape through small pores in the latex which are larger than the helium atoms. Balloons filled with air usually hold their size and shape much longer.
Even a perfect rubber balloon eventually loses gas to the outside. The process by which a substance or solute migrates from a region of high concentration, through a barrier or membrane, to a region of lower concentration is called diffusion. The inside of balloons can be treated with a special gel (for instance, the polymer solution sold under the "Hi Float" brand) which coats the inside of the balloon to reduce the helium leakage, thus increasing float time to a week or longer.
Source: http://en.wikipedia.org/wiki/Balloon
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